Well, like Jpal said, brass may contain lead, which you obviously don't want in your beer. Furthermore, brass seems to corrode or wear very fast. In no time at all, that brass will look horrendous, while stainless steel just keeps shining away. Also, in the food industry, stainless steel is pretty much the only thing acceptable to use, so just go stainless. In your question you asked what makes a Hot liquour tank valve, or mash tun valve different than any other valve. Well the answer is, nothing. You will see brew stores sell brass and stainless alike, these valves are not made specifically for the homebrew application. Homebrewers are simply using what is available on the market and putting it to use in their own way. Good Luck!