The accuracy will be based off the indicating device. The thermocouple really doesn't have a degree of error due to the way it operates. Thermocouples are made of 2 metals or alloys that are fused. When there is a temperature change the metals expand or contract at a specific rate for the type of metal. This difference causes a small voltage to be developed. That voltage is then interpreted by your readout device. In short the thermocouple operates by principles of physics and chemistry, therefore no measurable error.