I've made some homemade PBW, and it was super simple to put together.
My local grocery store has its own version of Oxiclean Free (identical recipe -- no perfumes or chlorine), so I grabbed that and a 4lb bag of TSP/90.
Easy mixture of 3.5lbs Oxi-free to 1.5lbs TSP/90, mixed together thoroughly. I use it all the time, no issues whatsoever.
Curious how you mix these up, so that they're well integrated. Just dump in a bucket and shake? (I would think that this would not mix well). Or, mix a little of each, alternating, and close/shake at various point along the way? Or something else?