It might be the better deal from the perspective of "hey, double the tubing for less than double the price". However there are a couple of other things to look at.
1. Do you really need more than 25' of tubing? A longer tube has more surface area to absorb more heat, but that only makes a difference as long as the temperature of the water is lower than the temperature of the wort. If the outflow temperature for 25' and 50' isn't significantly different, you've gained nothing with the extra length.
2. How well constructed is the 50' chiller compared to the 25'?
3. What about the hoses connecting to the chiller - are they the ones you need for your setup?