The efficiency of your mash is what it is, in percent, as a result of the types of grain you use, how your grains are milled and mashing technique and equipment, etc. However, continuing to sparge and collect beyond your preboil target volume, will carry more sugar to your boil kettle and increase your volume while decreasing the OG of the preboil wort. Mash runnings generally should not be collected once OG drops below 1.008-1.010 to reduce an increase in tannins. Once you have collected all you want, begin boiling and boil to you preboil target volume, the add your first (typically T-60) hop additions and follow your recipe. Boiling more than 60 minutes will decrease DMS, at the risk of carmelizing the sugars and darkening the wort with slight changes in flavor. However, the best method, remains an efficient mash and collecting the correct amount of preboil volume for the recipe.