Since I've seen many state DME darkens with a longer boil, and I haven't experienced it, I thought I'd do a quick test today. It's by NO means scientific! I only had 2 lbs of Briess Wheat DME available so this is what I did:
I brought 1 gallon of water to a boil, shut off the heat, and stirred in 1lb of DME. I then brought it back to a boil and timed 10 minutes. Then I shut off the heat and cooled it in the sink. After cool I took a pint glass sample.
Next, I brought 1 gallon of water to a boil, shut off the heat, and stirred in 1lb of DME. I then brought it back to a boil and timed 60 minutes. Then I shut off the heat and cooled it in the sink. After cool I took a pint glass sample.
Now, I know I know, the best approach would be to have boiled one gallon of water for 50 minutes then added the DME for the 10 minute test - BUT, I didn't have the time to test for nearly 3 hours so I did it this way. The results are pretty similar anyway because at the end I also compensated for the boil off.
The first pic shows the two pint glasses next to one another. The one on the left is the 10 minute boil. The one on the right is the 60 minute boil. Take note how they really aren't worlds apart in darkness and you can see the 60 minute one is more opaque, hence adding to a darker appearance, due to the boil off. If I had done a 50 minute boil off for the 10 minute test I am fairly certain the results would match identically. The second pic shows the 60 minute boil with top off water to get it back to 1 gallon. This is a bit unfair since I don't know what the boil off was for the 10 minute boil but it couldn't have been too much so I didn't take it into account. Though as a result you can see the pint on the left (the 10 minute boil) is ever so slightly darker so a mismatch in the top off water is likely the reason.
Again, this test was NOT meant to be scientific or definitive proof of anything. I just did this out of curiosity and so far from my past batches it seems to agree with my personal opinion that DME does not really darken more for a full length boil - or if it does it's rather negligible. Oh, btw... the hefe on the left is a 5.5lb (5 gallon batch) all Wheat DME hefe I made. Just put it there to show the color after fermenting.
I brought 1 gallon of water to a boil, shut off the heat, and stirred in 1lb of DME. I then brought it back to a boil and timed 10 minutes. Then I shut off the heat and cooled it in the sink. After cool I took a pint glass sample.
Next, I brought 1 gallon of water to a boil, shut off the heat, and stirred in 1lb of DME. I then brought it back to a boil and timed 60 minutes. Then I shut off the heat and cooled it in the sink. After cool I took a pint glass sample.
Now, I know I know, the best approach would be to have boiled one gallon of water for 50 minutes then added the DME for the 10 minute test - BUT, I didn't have the time to test for nearly 3 hours so I did it this way. The results are pretty similar anyway because at the end I also compensated for the boil off.
The first pic shows the two pint glasses next to one another. The one on the left is the 10 minute boil. The one on the right is the 60 minute boil. Take note how they really aren't worlds apart in darkness and you can see the 60 minute one is more opaque, hence adding to a darker appearance, due to the boil off. If I had done a 50 minute boil off for the 10 minute test I am fairly certain the results would match identically. The second pic shows the 60 minute boil with top off water to get it back to 1 gallon. This is a bit unfair since I don't know what the boil off was for the 10 minute boil but it couldn't have been too much so I didn't take it into account. Though as a result you can see the pint on the left (the 10 minute boil) is ever so slightly darker so a mismatch in the top off water is likely the reason.
Again, this test was NOT meant to be scientific or definitive proof of anything. I just did this out of curiosity and so far from my past batches it seems to agree with my personal opinion that DME does not really darken more for a full length boil - or if it does it's rather negligible. Oh, btw... the hefe on the left is a 5.5lb (5 gallon batch) all Wheat DME hefe I made. Just put it there to show the color after fermenting.