Iodine will tell you if starch is present, but starch conversion to sugar is only part of what we're trying to accomplish. As alpha amylase converts starch to sugar, beta begins breaking the more complex carbohydrates into short chain sugars that are more fermentable. Since these two primary enzymes are most active at different temperatures, we can somewhat control the fermentability of our wort with temp and time. If we only used iodine to tell us the mash is done, we may have a wort that will barely ferment leaving a cloying sweet beer.
+ eleventy billion!