If you use your hydrometer too hot you can melt the wax plug in it which can throw it off. Refractometers are great and I use one hot side, but you can also put some wort in a cocktail shaker and swirl in a bowl of ice water for very speedy chilling. About 1-2 minutes. My stick thermometer fits right in the holes strainer holes of the shaker it is really easy, just don't burn you hand on the shaker at the beginning.
Also if you are using this to see if you are on your numbers make sure you take the expansion of the liquid at the high temp into account in your volume calc. On my 10 gal setup I typically collect 12.5 gallons at boil but to figure my gravity I calculate at 12 gallons. There is roughly a 4% increase in volume at boil.