He mentioned Agave. Agave has a lot less sugar in it than honey. I am wondering if it will ferment as well as honey. I would think that it would leave some of that flavor. That is just my thought though.
Yeah, I'd put it in at flame-out or sometime between flameout and the chill (though, I wouldn't recommend the second one). I want to add honey to an IIPA of mine to thin it out and add a small undertone of flavor, but I'm still 'in the woods' about the whole thing. I'm thinking about adding 1lb of honey to a 8-9% (at 65-75% efficiency) to bump up the % to 9 and to dry it out. A lot of IIPA's add dextrose corn sugar to dry it out, but I'm thinking honey will add a small bit of flavor and work the same as corn sugar.
Consider making a IIPA if you want an emphasis on honey. You could probably put in 2.5-3lbs that way, if you really wanted to.. I'd probably suggest mashing at a higher temp though.
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