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PBW solution turned blue?

Discussion in 'Equipment/Sanitation' started by PlexVector, Mar 10, 2015.

 

  1. #1
    PlexVector

    Mellow Goose Brewing  

    Posted Mar 10, 2015
    I have a Marks Keg/Fermenter cleaner and the well water was clear when it started and then when I came back from dinner it had turned swimming-pool blue. I used one tablespoon/gal of PBW and I am recirculating it through my RIMS to keep it around 120F. I also rigged it through my plate heat exchanger to clean it again in prep for the a brew day this week. Could it be a reaction with the copper in the heat exchanger? The RIMS has an ultra low watt density heating element that is for high lime content water, which is the dark color rather than bright SS. Should I be using the SS heating element?

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  2. #2
    jtratcliff

    Well-Known Member  

    Posted Mar 10, 2015
    My DIY PBW (oxiclean & TSP90) gets fairly bluish when I first mix it up with city tap water.

    Do you have pH test strips? As long as you're under 3, you should be fine.




    Edit to add:

    Ignore this. I'm an idiot. It's star san that needs a pH under 3, as pointed out below.
    I still get slightly bluish water from DIY PBW in a white bucket, though...
     
  3. #3
    PlexVector

    Mellow Goose Brewing  

    Posted Mar 10, 2015
    Everything had a basic cleaning from the last brew day, but I wanted to give everything another hit since I had not brewed in a while, so the pH should have been okay. I had some old test trips that will go that low I think. I'll test it. My well water is just a tad acidic anyway. I don't remember it being that blue, although this is the first time its been in a white container.
     
  4. #4
    Hopper5000

    Well-Known Member

    Posted Mar 10, 2015
    PBW is a base. I think you might be thinking of Starsan having to be below 3?

    Mine has turned blue before too. As long as it cleans I don't think you have anything to worry about.

    You could always email the manufacturer...
     
  5. #5
    flars

    Well-Known Member

    Posted Mar 10, 2015
    The presence of copper will show a blue flame in gas chromatography. Your water source could be part of the reaction.
     
  6. #6
    Shooter

    Almaigan Brewing Co.  

    Posted Mar 10, 2015
    I suspect the copper in the exchanger is the problem. I notice I get a blue color initially when clearing my nitro faucet after letting it soak with cleaner. This doesn't seem to happen when soaking it with anything else.
     
  7. #7
    IslandLizard

    Progressive Brewing Staff Member  

    Posted Mar 10, 2015
    Amazing!

    I recirculate homemade PBW through my DudaDiesel plate chiller for up to an hour at 160-180°F. The PBW water always turns yellowish/brown from wort and hops deposits in the chiller. Yours must be ridiculously clean to see this.

    Some Copper salts tend to be greenish or blue. Most plate chillers we use are brazed with copper, so that could be a source. Did you store your chiller filled with Starsan (an acid)?
     
  8. #8
    doug293cz

    BIABer, Beer Math Nerd, ePanel Designer, Pilot Staff Member  

    Posted Mar 10, 2015
    Copper ions in a solution will definitely turn it blue.

    Brew on :mug:
     
  9. #9
    wardens355

    Supporting Member  

    Posted Mar 10, 2015
    If it turns blue, I think it means you're pregnant.
     
    Brauer, JonM, jtratcliff and 2 others like this.
  10. #10
    1977Brewer

    Free Dan Hess.

    Posted Mar 10, 2015
    90% certain your chiller just failed a drug test.
     
  11. #11
    PlexVector

    Mellow Goose Brewing  

    Posted Mar 10, 2015
    Yep, PBW is a strong base. So, it may be copper hydroxide. Does anyone know if this is detrimental to the plate exchanger?


    EDIT:
    Okay, I found this in an old thread. I guess I will do a good rinsing before I use it again. Don't know what the sodium bisulfite does chemically to the copper hydroxide.
     
    Last edited: Mar 10, 2015
  12. #12
    PlexVector

    Mellow Goose Brewing  

    Posted Mar 10, 2015
    This one is a dudaDiesel. After the last brew day it got a good cleaning. I would hook it up to the sink hot water with silicon hose. pinch the output hose and the input hose would swell and build pressure and then release. It spit like crazy. then reverse direction. It was amazing as to what came out. Did that about 15 times before running clear.
     
  13. #13
    PlexVector

    Mellow Goose Brewing  

    Posted Mar 10, 2015
    if it doesn't start behaving I'll have to take its lava lamp away!:fro:
     
    Newsman likes this.
  14. #14
    IslandLizard

    Progressive Brewing Staff Member  

    Posted Mar 10, 2015
    I have the short and tall chiller (30 plates) and must have more deposited gunk in there than you do. After the back and forth purging runs clear, my PBW always comes out a shade of yellow/brown, probably masking the blue copper salts. Is this a wake-up call?

    I used to store mine filled with Starsan, until I read that the copper brazing can be attacked by the acid. So I shake it dry now. I bake mine regularly at 350-400°F, with bread or pizza, to sterilize.

    Have you tried with just Oxiclean by itself? My home compounded PBW only contains generic Oxi-product and Sodium Metasilicate (TSP-90). There's plenty of OH- available in those alkaline cleaning solutions to attack the Cu.

    Real PBW contains Sodium EDTA, a strong metal ion sequestering agent. It can suck the metals out of glass, over time.
     
  15. #15
    PlexVector

    Mellow Goose Brewing  

    Posted Mar 10, 2015

    PBW is probably being used in copper kettles and fermenters. I would think this would not be a new subject.
     
  16. #16
    PlexVector

    Mellow Goose Brewing  

    Posted Mar 10, 2015
    Before things get out of hand I did a quick google on PBW and copper. Sounds like PBW is okay with copper and that the copper brazing inside of my chiller is probably nice and shinny in that the PBW removed some of the oxide layer.
     
  17. #17
    IslandLizard

    Progressive Brewing Staff Member  

    Posted Mar 10, 2015
    Oxide layers tend to protect the underlying, more reactive bare metal. So dissolving it still corrodes, slowly but surely. We probably shouldn't worry so much and stick to more basic things we understand better, like brewing beer! :mug:
     
    PlexVector likes this.
  18. #18
    jtratcliff

    Well-Known Member  

    Posted Mar 11, 2015
    D'OH!

    Absolutely correct!:smack:

    My DIY PBW is still blue-ish in a white bucket though :D
     
  19. #19
    maierhof

    Well-Known Member  

    Posted Mar 11, 2015
    I have also seen this - as my carboy/keg/keggle cleaner has a copper shaft attached to the pump itself. It is the copper and time that you had it cleaning the copper.

    Shorten your cleaning cycle if you don't want the color, but IMHO - just rinse the s#!t out of it and you are done. Nothing to fret over.

    At first when I saw this color I thought - omg I broke a seal in the pump - and was just stumped trying to figure out how this happened...

    Then I got a piece of copper and stuck it in small pool of 120*F PBW for a few hours - there you go. :mug:
     
  20. #20
    PlexVector

    Mellow Goose Brewing  

    Posted Mar 13, 2015
    Thanks all. Ignorance is not bliss after all. At least not in home brewing. I solved the problem by not using white containers. :)
     
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