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Adding chelator (citric acid?) to oxygen cleaner

Discussion in 'Equipment/Sanitation' started by dirkomatic, Oct 23, 2013.

 

  1. #1
    dirkomatic

    Well-Known Member

    Posted Oct 23, 2013
    Can one of you chemistry type people tell me if I could just add some powdered citric acid to Sun Oxygen Cleaner to act as a chelator so there's less/no white scale left behind?

    Thanks!
     
  2. #2
    jbaysurfer

    Former future HOF Brewer  

    Posted Oct 23, 2013
  3. #3
    dirkomatic

    Well-Known Member

    Posted Oct 23, 2013
    Yes. I've read that thread and there is good information, but no one actually states any facts about if it's safe and how much to use... It's a bunch of speculation about what it could be....
     
  4. #4
    Wynne-R

    Well-Known Member

    Posted Oct 23, 2013
    I’m not a chemist, but I did take a few courses. The problem with citric and Oxi is that you are adding acid to an alkaline cleaner, you would need a bunch to make it work.

    When I say Oxi, I mean generic. Name brand Oxiclean contains detergent, which we don’t need. It just makes everything slippery. Jbaysurfer, good link, but I don’t see the need for surfactant. It breaks up fat, but there ain’t no fat in beer.

    Side rant; it makes me crazy that Oxiclean is usually misspelled.

    I use PBW as a water softener, it contains chelators, EDTA I believe. Use just enough PBW to neutralize the hardness and when it’s thoroughly dissolved, add the Oxi.

    It depends on your water how much to use, you need to play with it and see what works. My water is 100 ppm alkalinity and I use 5 grams (½ tbsp) PBW in about two gallons. Then use about half as much Oxi as usual.

    I find the combination works better than either cleaner used alone and no limescale.
     
  5. #5
    jbaysurfer

    Former future HOF Brewer  

    Posted Oct 23, 2013
    Good stuff Wynne-R

    OP, I currently use Oxi-free mixed with Sodium Metasilicate, but I do not have a chelating agent in my mix, and with my hard water, I do get scale (if I let stuff soak for more then 45 minutes or so.

    I'm going to try Wynne's solution. Regarding "facts" well people have stated that it "can be used" and that some commercial detergents contain citric, so there's that, but the "if it's safe" part I think you're going to be taking some risk on your own there. I wouldn't tell any internet stranger that a certain chemical mix is "safe" and I think actual chemists probably hold themselves to higher standards of care then I do.

    Best of luck. Maybe someone else will chime in, but so far, Wynne's suggestion seems to resonate as the most practical for my purposes.
     
  6. #6
    dirkomatic

    Well-Known Member

    Posted Oct 23, 2013
    Right, I mean I remember enough to know that acid + alkaline kind of offset one another and/or cause a bad reaction.... But it seems all chelators are acid of some sort and PBW contains a chelator and is an alkaline cleaner. Does anyone know chemically how that works?

    And agreed... Generic "Oxygen Cleaner" is what I'm talking about. There's no need for surfactant of which I am aware.
     
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