I'll start off by saying that I'm new to this and this is going to be my second batch of beer (Fat Tire Clone). I ordered the Wyeast American Ale II 1272 from my LHBS and made a starter wort following the ratio of 3/4 cup light DME to 2 cups of water and boiling for 15 minutes. I pitched the yeast on Thursday night and doubled the starter yesterday morning shaking every few hours to give it some oxygen. This morning I put the starter in the fridge with the intention of leaving it there for 24 hrs and brewing the beer tomorrow. Everything seemed to look great, it had a nice caramel milky color to it, and the yeast layer on the bottom looked fine until I checked on it about an hour ago. There was a dark almost gray layer that had formed. Did I screw something up.