I'm tempted to try this. My motivation is not to clear haze though. I've never brewed a pumpkin ale, but I read lots of stories about stuck mashes. I'm tempted to add the pectic enzyme to help break down the cellular structure of the plant cells
Botany lecture time. A anology to describe the cell walls of plant cells is to think of reinforced concrete. Cellulose (and Hemicellulose) is the re-bar that provides the strength and pectin (and some other compound) are the "glue" that holds the rebar in place.
So in theory, adding a pectinase should facilitate greater breakdown of the cell walls and allow better access of the barley enzymes to the starches inside of the cells.