The best way is not to boil DME or liquid extract at all, just add at the end of boil time, and let steep for a few minutes. Hops and mash from grain does need to be boiled, but during the manufacturing process to concentrate extract and DME they have already literally had the hell boiled out them. Heres a quote from an article in BYO mag website. "You will note that I do not call for boiling the malt extracts. One of the more recent trends in extract brewing is to not boil malt extracts that were boiled prior to being concentrated."