While you ferment, you're venting off excess CO2/gasses. IF you go and capture (assuming from the start) you'll get more than just CO2 in your containment, or into the beer. This is one of the reasons why you don't just capture the CO2 from fermentation and use it. You need to filter it, and then compress it so that you can push it into the finished beer.
IMO, this isn't a project for anyone not 100% familiar with all that's involved.
As for the previous comment about 100 psi being too close to the 130 psi listed maximum... At 130 psi, the release/safety valves will trigger. IF your keg is in good condition, it shouldn't fail. Not to say it won't, due to a flaw or damage, but I'd be less concerned about that. Besides, I've read [before] that yeast pretty much stops around 30psi. So the chances of getting even close to the previously listed 100psi target is a pipe dream (IMO).
Seriously, IF you really, really, really want to do this, research all that's involved first. Don't go into it half-assed since that could be dangerous. Although you could get closer to the results you desire by fermenting under pressure. Although, I would advise finding a better source of CO2 in your area first. With what it could cost to rig up a system to capture CO2, you could probably purchase CO2 for many years before you come even close to that level. If you can't recover/save the expense of making the system within a couple of years (<3 being my normal guide) then I wouldn't. Unless you have that much money to blow.
TheCarnie said:
These are the answers I'm looking for. Total assumption, but I figure if <5oz of corn sugar can carb a keg with 15psi in the headspace, then enough pressure to serve it as well doesn't seem to improbable.
Using more sugar in order to try to capture excess CO2 means you'll be very over-carbonated. IMO, more trouble than it's worth.