If you're brewing on a stovetop, this may be one time that a keggle is not an ideal solution. They're obviously big, heavy, and bulky - add six or seven gallons of wort to the mix, and that's not something I want to wrestle on top of the stove, and I've concerned that it would damage the stovetop.
As to the other concerns, the inside should be fine, they're SS.
I haven't heard of too many people who use their brew kettle as their mash tun. You would still need to have another vessel to collect the wort while you cleaned out the grain, then you'd have to move the wort again back to the brew kettle. I'd spend the $40 - $50 to put together a cooler-based mash/lauter tun, myself.
EDIT: Oh, and welcome to the forums!
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