There are three scales on your hydrometer. One shows Specific Gravity (Specific Gravity readings are taken before starting and after fermentation has finished. Original Gravity {OG} beforehand, Final Gravity {FG} at the end to determine whether fermentation has been completed, or not, and it's safe to bottle).
Another scale shows the potential Alcohol By Volume (ABV) that would result if the sugars were to attenuate fully and be converted to alcohol with a Final Gravity of 1.000.
The 3rd scale shows the volume/weight of sugar per litre.
You're most interested in the scale for ascertaining Specific Gravity.
That's the one that starts at 0.090 at the top the descends in 5 X 0.002 intervals through 1.000 (then there's no 1 but it carries on down) 010, 020, 030, 040, etc etc.
Here's a couple of links to help.
How to Brew - By John Palmer - Appendix A - Using Hydrometers
Stevenson Reeves - How to use a hydrometer