I used to use two pots and split the boil when I first started. It works fine.
You will want to boil the wort for an hour, in both pots because you want to kill any bacteria from the grains, boil off DMS precursors, etc. You can probably go less than an hour on the second pot, but 10 minutes isn't enough.
You'll want to start with about 7 (US) gallons at the beginning, to allow for boil off. If you have two pots that could each start with about 3.5 gallons, you could split the boil and hops evenly and that would be ideal. If you don't have two pots that big, or two big enough burners to do both of the same size, you could do what you are suggesting. Your hops utilization will be slightly different, though.
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