I've never calculated it, but a pound of extract syrup seems to run about a pint in volume (i.e., when I got 7# of syrup, it nearly filled up a gallon bucket).
For a 5.5 gallon batch, I usually shoot for a seven gallon start for my boil. I add 5 gallons to the kettle, bring that up to about 180 or so, cut the fire, add my extract and reconstitute fully, then top off with more water to my desired spot. If I steep grains, I do that with an appropriate volume of water, add the balance of the first 5 gallons, and go from there.
And, if you are doing full wort boils, don't worry about darkening or scorching your extract. Just get it fully reconsituted and enjoy a full boil. You will be happier later on.
TL
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