Campden is not strong enough (unless you add copious amounts rending it undrinkable) to kill off commercial strains of yeast. It will kill most wild yeast and most bacteria that wine makers are apt to encounter if added to the must prior to pitching commercial yeast. It's also not strong enough that it would kill off an active wild yeast ferment. Campden is a chemical, potassium meta-bisulfite, that inhibits oxidization of the wine during racking and aging in bulk or bottle. At this point in the game the alcohol is providing the sterile environment and the sulfite is protecting the alcohol.
If you want to inhibit fermentation in a sweet wine as it ages then you would add potasium sorbate to neuter the yeast (won't reproduce) and potasium meta-bisulfite to prevent oxidation. Sorbate works better when used with sulfite.
Since your friend is trying to use wild yeast the campden (sulfite) would hinder fermentation if added to the must. So add it after fermentation is complete.
From looking at your posted recipe, 5 qts of blackberries is no way near enough to make 5 gallons of wine. It takes 3 to 4 pounds of blackberries and up to 6 for a heavier bodied wine per gallon, so he should be using 15 to 30 lbs of berries for 5 gallons. What he'll end up with is a light berry colored alcohol drink. Something is off there.
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I used to have a six-pack, but now I have a keg.
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