I'm trying a cereal mash for some un malted pearled barley in another brew. not expecting much utilization out of it other than body & head retention, and maybe some flavor. Buckwheat has a strong sharp slightly sour addition to flavor, thought you may get same by using the cereal mash technique to gel starches to a some what usable adjunct.
Not a gluten free guy but pop over here for some interesting ideas... like I said RJ rockers here in SC may be able to help with a simple as a email. I had a question about one of their brews as a home brewer and they promptly responded.
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