If it were me, I'd probably make sure the starter is nice and shaken and do my best to split the starter amongst the two fermenters. You can decant, if you prefer, but just make sure it's well shaken so you get a reasonably even distribution of yeast. I prefer to add my yeast into the fermenter, rather than my kettle, if only because the larger hole in the kettle makes more room for nasties to get in than the relatively small hole of a fermenter.
For a 10 gallon batch split amongst fermenters, you'll want twice the amount of yeast, so that means doing a 2L+ starter or, better yet, a stepped starter.
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