So I made the mistake of tasting my Belgian Single 2 days into fermentation (Wyeast 3787). I know, RDWHAHB. It's just not what I do

There is definitely an off flavor, and my guess is that it's Diacetyl or DMS. To be perfectly honest, I just don't have much experience with either. You should be able to tell the difference between Butter and Cooked Corn, but I guess I just don't have the taste for them.
I'm leaning towards Diacetyl because I figured that since it's made during fermentation that I wouldn't have tasted anything in the hydrometer sample before fermentation which I didn't. I would have tasted DMS since it's made in the boil correct?
Thanks for the help