At the risk of sounding condescending, malt gives that malty flavor, but there are a lot of facets to "maltiness" (i.e., sweet, bready, toasty, nutty, roasty, grainy, to rattle off a few). Since you mention Munich, I suspect you are aiming at those toasty, nutty, and melanoidin malty flavors and aromas.
Yes, Munich gives that sort of maltiness in spades. Vienna, British pale malt, and domestic "Special" pale malt give a little less. Typical domestic pale malt gives even a little less, and Pilsner malt gives less still. All those other malts give some combination of other "malty" flavors and aromas, though.
TL
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