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Originally Posted by modenacart
You are arguing semantics with air not holding water. A colder ambient temperature would increase heat losses thus less energy going into the boil, thus less boil off. I am sure this is almost negligible anyways.
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Call it semantics if you want, but the only effect the air has is it's ability to affect the temperature of the water vapor.
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Originally Posted by modenacart
Also the moisture gradient and capacity of the air to hold water vapors does matter because it gives the water vapors a place to go allowing for more to boil off more readily.
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Well, only if you disregard the diffusive properties of gases. The air doesn't give the water vapor "a place to go", it's a vapor that will diffuse on it's own, regardless of the supposed "holding capacity" of the air. This is especially true when you consider that water vapor is actually lighter than air at the same temperature, so it will rise and diffuse even quicker at boiling temperatures.
Again, evaporation is a constant at a given temperature, it's the condensation that matters. You could make an argument that the cooler air will cool the water vapor quicker, making it recondense back into the kettle, but when you have rising steam from the boiling wort, I don't think it will be significant.