A follow up: I figured out the problem..
I am an electric brewer, and had not realized my elements had developed a "crust" or several layers of gunk from not scrubbing the elements after brewing - I only rinsed them off.
The encapsulated gunk layers began to scorch, thus causing the burnt/smokey/ashy smell. There actually was a black layer of burnt crust that started to flake off the elements.
Unfortunatley, I had to ruin another batch to realize this.. As I was collecting my 1st runnings from a batch this weekend, I turned on my elements. The "steam" that was rising from the wort made me do a 2nd take - it wasn't steam, it was small puffs of smoke rising from the wort. It was a burnt smell.
Problem solved!
Although, when weighing my grains at the LHBS, I tasted all the grains - not one tasted smokey or ashy, but I do agree Yooper, the Biscuit does have a rather "dry" flavor/aftertaste.
Anyway, thanks for all the help - I'm replacing my elements this week and will be back on track - and scrubbing the elements clean after each use..
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