When a beer is bourbon barrel aged it would only touch the charred inner surface. Those chips would have some of that, but it would also be partly raw wood where the wood was split, and partly the outside of the barrel.
I’ve had good luck soaked heavy toast American oak cubes in bourbon for a couple months, then adding the cubes along with a few shots of fresh bourbon to the beer in secondary.
Smoking some malt with it on the other hand sounds like a great idea.
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