That green discoloration on your copper is a little bit worse than the typical light oxidation. Here is what John Palmer says:
Quote:
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"You should be aware that copper can develop a toxic blue-green oxide called verdigris. Verdigris includes several chemical compounds--cupric acetate, copper sulfate, cupric chloride, etc.--and these blue-green compounds should not be allowed to contaminate your beer or any other food item. To clean heavy oxidation, including verdigris, use vinegar or oxalic acid-based cleansers like Reverware Copper and Stainless cleaner."
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So vinegar is still fine, but don't dilute it down much and make sure to get all those green oxides off your chiller before you use it.