Should I be worried about my tanks sitting in my garage year round? It gets 95F+ in there in August!
As to vehicle safety, I had a 25# CO2 tank in my car when it rolled twice. The tank started in my backseat, and ended up in my front passenger seat. I don't know how I didn't get whacked by it...oh and my little .22 rifle that was in the back ended up sticking out the windshield in front of my seat.
Here's a picture of how it sat:
